城市空间与其使用价值——汕头中山公园的城市空间意义

文章通过论述汕头中山公园在策划背景、分析论证、用地选址和大规模建设各方面，是如何作为城市空间来体现其社会使用价值，来探讨城市空间产生过程中错综复杂的政治、经济、社会和文化多方面力量的博弈，以及城市社会和空间使用的相互关系。     

土壤中石油污染物的脱附过程

文章中主要采用有机溶剂萃取法（OSE）对高浓度石油污染土壤进行修复，经过精馏操作，有效回收原油，建立脱附等温曲线，研究了石油污染物在土壤-有机溶剂两相间的迁移规律。     

Differences between internal and external hydrogen effects on slow strain rate tensile test of iron-based superalloy A286

To investigate the evaluation method of hydrogen compatibility of A286 superalloy in high pressure hydrogen gas, SSRT tests of hydrogen-charged specimens were conducted at ambient temperature at various strain rates. The relative reduction in area (RRA), one of the ductility parameters, was determined. The hydrogen content in the hydrogen-charged specimen was the same as the equilibrium hydrogen content on the specimen surface at 150 °C in 70 MPa hydrogen gas. The strain rate dependence of RRA was smaller than that of RRA obtained in 70 MPa hydrogen gas at 150 °C. All the hydrogen-charged specimens showed slip-plane fractures in the grains in their cores. However, the specimens in 70 MPa hydrogen gas at 150 °C showed fracture surfaces morphology ranging from dimples to quasi-cleavages and intergranular fractures with decreasing strain rate. These dissimilarities are expected to arise from differences in the hydrogen concentration behaviors of the specimens during the deformation process.     

Solution plasma-assisted preparation of highly dispersed NiMnAl-LDO catalyst to enhance low-temperature activity of CO2 methanation

In this work, the solution plasma-assisted method was used to prepare NiMnAl-LDO (layered double oxides) catalysts with different treatment times, which were used for the CO₂ methanation reaction. Solution plasma treatment can enhance the dispersibility of the catalyst, create oxygen defects and improve the chemical adsorption capacity of the catalyst. The results show that the low-temperature activity of the catalyst has been improved after the solution plasma treatment. We demonstrate that the NiMnAl-LDO-P(20) catalyst with high dispersion has the highest catalytic activity in CO₂ methanation (81.3% CO₂ conversion and 96.7% CH₄ selectivity at 200 °C). Even though working for 70 h, the catalyst is still highly stable. This work provides a great promise for improving the low-temperature activity of Ni-based catalysts.     

Experimental study on vibration-induced clamping force reduction in fuel cell structures

When applied to transportation systems, fuel cell structures are exposed to external mechanical disturbance including shocks and harmonic excitations from operating components. To minimize performance degradation from machine operations, the fuel cell structure needs to be examined via vibration reliability tests. In this study, the reduction in the clamping force of the stack by random vibrations was investigated by experiments. The stack mass and gasket were clamped with bolts for vibration tests. The vibration induced shear movements between clamped stacks. To estimate the vibration input magnitudes, the Dirlik method was used. The reduction in the stack clamping force was estimated using the Basquin's power law. The clamping force decreased by the shear vibration input to the stack structure. The degree of clamping force reduction was larger for the heavier stack. When the stacks were separated by the gasket the reduction became smaller. Through the Dirlik method, the vibration reliability of the stack was evaluated. This information provides severity of the external vibration on the stack functionality.     

重复采动覆岩裂隙率空间分布相似模拟研究——以陕北矿区为例

由于水资源短缺,陕北矿区利用采空区储存矿井水进行再利用,采空区储水量与采动裂隙空间分布密切相关,为准确预测采空区储水量,基于工作面上覆岩层断裂分带划分结果,确定煤矿地下水库的主要储水空间为垮落带与断裂带的裂隙空间,建立了采动覆岩裂隙率空间分布的计算方法,采用相似模拟试验得出了柠条塔矿1^-2煤和2^-2煤重复采动后上覆岩层的下沉曲线,计算出重复采动覆岩裂隙率在垂直和水平方向的空间分布情况。结果表明:沿垂直方向,随着高度增加,覆岩裂隙率逐渐减小,1^-2煤开采后岩层裂隙率由1.87%逐渐下降为1.18%,2^-2煤开采后,裂隙率由12.85%下降为4.11%;沿水平方向,垮落带、断裂带和弯曲下沉带的裂隙率在采空区边缘附近都会产生2个峰值,并且峰值位置逐渐向采空区中央移动,1^-2煤开采后,中间压实区的最大裂隙率为1.21%,两边离层区的最大裂隙率为2.19%,2^-2煤开采后,压实区和离层区最大裂隙率分别为16.1%和6.54%;重复开采后,上覆岩层的裂隙率显著增加,有...     

Effect of aging time on discontinuous precipitates,continuous precipitates and mechanical properties of AZ80A magnesium alloy

The evolution of precipitates and mechanical properties of AZ80A magnesium alloy with aging time was studied by in situ observation with SEM, TEM and tensile testing. The results show that the continuous precipitation (CP) phases near the reaction front (RF) are replaced by the discontinuous precipitation (DP) phases at the early aging stage. In DP regions, the elliptical phases coarsen obviously with the increase of aging time, which results in a slightly slow reduction of the intracrystalline hardness of DP regions. In CP regions, some small plate phases reprecipitate simultaneously with the growth of the initial precipitates, which contributes to a slight increase in the intracrystalline hardness in CP regions at the later aging stage. The aging hardening of DP regions is faster and stronger than that of CP regions. However, the age strengthening of CP regions not only compensates for the overaging softening of DP regions but also improves the strength of the alloy.     

杏鲍菇富硒蛋白的营养结构特性及对铅毒性的缓解作用

铅主要通过饮食进入人体并在体内积累，对人体免疫和代谢等系统造成损伤，补充硒可以显著改善铅暴露对机体的危害。本研究以杏鲍菇富硒蛋白（selenium-enriched protein from Pleurotus eryngii，SePEP）为原料，通过高效液相色谱-电感耦合等离子体质谱联用技术、傅里叶变换红外光谱等测定蛋白硒形态及结构。通过细胞实验探究蛋白体外模拟消化产物对Pb2＋引起的RAW264.7细胞毒性的缓解作用。结果表明，SePEP硒含量为（360.64±3.11）mg/kg，硒形态主要包括硒代蛋氨酸（SeMet，（48.04±0.64）%（相对含量，下同））、硒代胱氨酸（SeCys2，（31.91±0.51）%）和甲基硒代半胱氨酸（MeSeCys，（14.65±0.36）%）。硒的添加显著促进了氨基酸的生成，改变了蛋白质的结构，α-螺旋结构相对含量由（20.30±0.87）%增加至（25.00±1.60）%，无规卷曲结构相对含量由（20.38±0.84）%减少至（13.85±1.66）%，总巯基与二硫键含量及表面疏水性均显著增加（P＜0.05）。添加75 μg/mL SePEP消化产物后，Pb2＋处理的RAW264.7细胞存活率由接近50%显著升高至（76.95±6.95）%，细胞培养液中乳酸脱氢酶释放量降低57.45%，并且3 种促炎细胞因子白细胞介素（interleukin，IL）-6、IL-8和肿瘤坏死因子α的释放受到显著抑制（P＜0.05），说明SePEP消化产物对Pb2＋暴露引起的RAW264.7细胞损伤有缓解作用。本实验研究成果可为研发安全、有效的改善铅毒性的功能富硒蛋白食品提供参考。